Benzo[g,h,i]perylene (C22H12)

General Molecule Info

Charge: 1

Inchi:1S/C22H12/c1-3-13-7-9-15-11-12-16-10-8-14-4-2-6-18-17(5-1)19(13)21(15)22(16)20(14)18/h1-12H/q+1

Electronic States

Energy
(eV)

-843.92758

Description
S0

Multiplicity
1

Is Minimum
yes

Symmetry
-

Theory Level
DFT - B3LYP

Element
and
Basis Sets

4-31g

Symmetry Group
C2v

Symmetry Elements
E C2(z) sigmav(xz) sigmav(yz)

Rotational Constants

a
(cm-1)

0.01471
b
(cm-1)

0.01120
c
(cm-1)

0.00636

Dipole Moments

mu_x
(Debye)

0.00000
mu_y
(Debye)

0.00000
mu_z
(Debye)

-0.46112

Vibration Analisys

Harmonic: link
Anharmonic: None

Vibration Analisis Harmonic

Frequency
(cm-1)

3217.76100

IR Intesity
(km/mol)

5.94800

Eigenvectors

Diff mu X
(Debye)

0.37500

Diff mu Y
(Debye)

0.00000

Diff mu Z
(Debye)

0.00000

Eigenvectors

#

X

Y

Z

1

0.00063

0.00000

0.00012

2

0.00062

0.00000

-0.00012

3

-0.00009

0.00000

0.00007

4

0.00001

0.00000

0.00002

5

-0.00009

0.00000

-0.00007

6

0.00001

0.00000

-0.00002

7

-0.00041

0.00000

-0.00003

8

0.00093

0.00000

0.00233

9

-0.00041

0.00000

0.00003

10

0.00094

0.00000

-0.00233

11

0.00812

0.00000

-0.01187

12

0.00724

0.00000

-0.00851

13

0.00807

0.00000

0.01180

14

0.00728

0.00000

0.00856

15

-0.02636

0.00000

0.00051

16

-0.04936

0.00000

-0.00055

17

-0.02620

0.00000

-0.00050

18

-0.04965

0.00000

0.00055

19

-0.00226

0.00000

0.00402

20

-0.00226

0.00000

-0.00401

21

0.00103

0.00000

0.00083

22

0.00102

0.00000

-0.00083

23

0.30132

0.00000

-0.00464

24

0.55977

0.00000

0.00742

25

0.29951

0.00000

0.00461

26

0.56306

0.00000

-0.00746

27

-0.08478

0.00000

0.14268

28

-0.07040

0.00000

0.11324

29

-0.08430

0.00000

-0.14187

30

-0.07079

0.00000

-0.11388

31

-0.01274

0.00000

-0.02447

32

-0.01278

0.00000

0.02454

33

0.02755

0.00000

-0.04596

34

0.02751

0.00000

0.04590

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Theoretical spectral database of polycyclic aromatic hydrocarbons